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11.
Yinhua Jiang ZhiYuan Peng Shuaibin Zhang Fan Li Zhanchao Liu Jianming Zhang Yan Liu Kun Wang 《Ceramics International》2018,44(6):6115-6126
The design and construction of efficient visible light responsive composite photocatalysts with intimate interfacial contacts in photocatalytic field have attracted huge interest. Herein, a double-shelled ZnIn2S4 nanosheets/TiO2 hollow composite single nanosphere (ZIS/TiO2) was first fabricated by a facile hydrothermal process, where 2D ZnIn2S4 nanosheets self-assembled on the external surface of TiO2 hollow nanosphere to form the double-shelled hollow single sphere. The morphologies, structures, optical properties of as-prepared double-shelled ZIS/TiO2 hollow nanospheres were characterized in detail. The photocatalytic activities of double-shelled ZIS/TiO2 nanospheres for the photodegradations of Tetracycline hydrochloride, Levofloxacin and Rhodamine B under visible light irradiation have been investigated. Compared to pure TiO2 and ZnIn2S4, the obtained ZIS/TiO2 samples have significantly improved photocatalytic performances. The most optimal photocatalytic activity of ZIS/TiO2-2 nanocomposite with 64 wt% ZnIn2S4 nanosheets coated is observed, and its degradation rate constant is 2.32 and 2.14 times as high as those of pure TiO2 and ZnIn2S4. The superior photocatalytic performance of ZIS/TiO2 nanocomposite can be ascribed to its unique double shell hollow structure and the synergistic effect between ZnIn2S4 and TiO2. Our result provides some guidance for designing novel morphologies of composite photocatalyst with good photocatalytic performance. 相似文献
12.
《Ceramics International》2020,46(9):13324-13330
Relaxor ferroelectric 0.75 Pb(Mg1/3Nb2/3)O3-0.25PbTiO3 (0.75PMN-0.25PT) ceramics with Mn-doping concentration of 0%, 1%, 2% and 3 mol% were prepared by two-step sintering. The phase composition, microstructure, dielectric property, ferroelectric property, piezoelectric property and electromechanical property were investigated. Results indicate that all ceramics exhibit pure perovskite phases and high density. Mn-doping induces some decrease in dielectric constant εr, dielectric loss tanδ, remnant polarization Pr, piezoelectric coefficient d33, and electromechanical coupling coefficient kp, while significant increase in mechanical quality factor Qm and the figure of merit (FOM) of 0.75PMN-0.25PT ceramics. For 3 mol% Mn-doped 0.75PMN-0.25PT ceramics, Qm enhances by 1449%, FOM increases by 923%, and tanδ decreases by 67%, which makes it more suitable for high power applications. Interestingly, double P-E loops are observed in 3 mol% Mn-doped 0.75PMN-0.25PT ceramics. The phenomenon was investigated by the symmetry-conforming principle of point defects and the internal bias field. 相似文献
13.
《Ceramics International》2020,46(13):21378-21387
A systematic density functional theory investigation of Cs2PbX6 (X = Cl, Br, I) double perovskites is presented. The lattice constants are computed after structure optimization and using Birch-Murnaghan equations, which agree to the experimental literature. The mechanical stability conditions satisfy Born criteria, and the ductile nature is evidenced by the calculated Poisson's (v) and Pugh's ratios (B0/G) because all three double perovskites exhibit values higher than the respective critical values v = 0.26 and B0/G = 1.75. A detailed study of the optoelectronic properties reveals these double perovskites as promising candidates for future optical devices due to their direct band gaps (within 0.45–2.54 eV) and large absorption coefficients 5.95 × 105 cm−1, which are suitable for solar cell applications. ZT calculations demonstrate minute variations within 200–800 K and computed parameter values are quite favorable for thermoelectric applications of these materials in the future. A p-type semiconducting nature is predicted by the computed thermoelectric properties. Additionally, computed refractive indices show Cs2PbBr6 and Cs2PbI6 exhibiting super-luminescent properties in the UV range. Therefore, the studied double perovskites provide further interest for future energy conversion and photonic based technologies. 相似文献
14.
A double optimal projection method that involves projections for intra-cluster and inter-cluster dimensionality reduction are proposed for video fingerprinting. The video is initially set as a graph with frames as its vertices in a high-dimensional space. A similarity measure that can compute the weights of the edges is then proposed. Subsequently, the video frames are partitioned into different clusters based on the graph model. Double optimal projection is used to explore the optimal mapping points in a low-dimensional space to reduce the video dimensions. The statistics and geometrical fingerprints are generated to determine whether a query video is copied from one of the videos in the database. During matching, the video can be roughly matched by utilizing the statistics fingerprint. Further matching is thereafter performed in the corresponding group using geometrical fingerprints. Experimental results show the good performance of the proposed video fingerprinting method in robustness and discrimination. 相似文献
15.
16.
The electrical characteristics of Al/strained Si-on-insulator (sSOI) Schottky diode have been investigated using current–voltage (I–V) and capacitance–voltage (C–V) measurements in the wide temperature range of 200–400 K in steps of 25 K. It was found that the barrier height (0.57–0.80 eV) calculated from the I–V characteristics increased and the ideality factor (1.97–1.28) decreased with increasing temperature. The barrier heights determined from the C–V measurements were higher than those extracted from the I–V measurements, associated with the formation of an inhomogeneous Schottky barrier at the interface. The series resistance estimated from the forward I–V characteristics using Cheung and Norde methods decreased with increasing temperature, implying its strong temperature dependence. The observed variation in barrier height and ideality factor could be attributed to the inhomogeneities in Schottky barrier, explained by assuming Gaussian distribution of barrier heights. The temperature-dependent I–V characteristics showed a double Gaussian distribution with mean barrier heights of 0.83 and 1.19 eV and standard deviations of 0.10 and 0.16 eV at 200–275 and 300–400 K, respectively. From the modified Richardson plot, the modified Richardson constant were calculated to be 21.8 and 29.4 A cm−2 K−2 at 200–275 and 300–400 K, respectively, which were comparable to the theoretical value for p-type sSOI (31.6 A cm−2 K−2). 相似文献
17.
为更深入并准确研究运行工况条件对多向扰流强化管CaSO_4污垢特性的影响,基于FLUENT软件的UDF功能构建了恒壁温条件下结垢传质过程与温度场的耦合作用关系,进一步采用田口法对运行工况致垢的贡献率进行了模拟比较,分析了贡献率较大的运行工况对污垢特性的影响。结果表明:溶液溶度致垢的贡献率占53.2%,而壁面温度、进口流速和进口温度的贡献率分别为22.2%、19.3%和5.3%;溶液溶度在4.0~2.5 kg/m~3,污垢热阻降低达90.47%,并且随溶度降低其相邻溶度间降低比例基本不变;壁面温度在340.0~315.0 K时,污垢热阻降低了65.22%,在前一阶段相邻温度间降低比例基本上不变,当达到320.0 K后降低明显;流速在1.0~2.5 m/s时,随流速的增加,污垢热阻降低68.65%,且随流速的增加,相邻流速间降低的速度明显减缓。 相似文献
18.
In this paper, a multiple model optimal tracking control (MOTC) design method for the double fed induction generator (DFIG) using correlative measured technique is proposed. The DFIG is represented by a third-order model, where electro-magnetic transients of stator are neglected. By using the correlative measured technique, the correlative measured matrix (CMM) of wind power system is obtained firstly. Then, a nonstandard state space equation of DFIG is obtained with the correlative measured vectors (CMVs), which reflect interactions between the DFIGs and grid. In order to cope with nonlinearities and continuous variation in the operating points, a multiple model design method is proposed in the discrete domain. The obtained control law, synthesized by using Bayesian probability, only depends on the local measured parameters. Hence, the MOTC can be regarded as a decentralized coordinated control, which can simplify the control structure and improve the transient stability of DFIG. To illustrate the effectiveness of the proposed MOTC strategy, simulations on a hybrid wind thermal power (HWTP) system are performed. The results show that the proposed MOTC strategy can provide acceptable performance throughout the whole operating region. Comparing to the conventional PID control, transient stability, damping, and fault ride-through capability of DFIG with the proposed MOTC design method have been improved effectively. 相似文献
19.
《International Journal of Hydrogen Energy》2022,47(6):3781-3790
A novel heterostructure of g-C3N4/ZnO/Bi4O5Br2 (ZB-3) was designed, and used in the microbial coupled photocatalytic fuel cell (MPFC). It can effectively improve electron utilization efficiency and pollutant degradation using this double Z-scheme heterojunction structure. The current–time (I–t) curves demonstrated that the current density of ZB-3 was higher than that of ZnO, ZnO/Bi4O5Br2 (ZB-1), g-C3N4/ZnO (ZB-2). Electrochemical impedance spectroscopy (EIS) indicated ZB-3 possessed the minimum charge-transfer resistance. This MPFC for degrading rhodamine B (RhB) and tetracycline (TC) under different conditions were developed using these materials. Even in the dark condition, MPFC with g-C3N4/ZnO/Bi4O5Br2 demonstrated 93% and 82% degradation efficiency for RhB and TC, respectively. Furthermore, the electron transport mechanism of the MPFC and ZB-3 were proposed. It paves the approach for more efficient pollutant degradation via MFC photocatalysis. 相似文献
20.
Imad Hussain S.N. Khan Eun Ji Kim So Eun Jeon Bon Heun Koo 《Ceramics International》2018,44(3):2892-2899
A systematic study focusing on the effect of Niobium (Nb) doping on the structural, magnetic and magnetocaloric properties of Ba2FeMoO6 samples is presented here. The samples of interest Ba2FeMo1?xNbxO6 (0 ≤ x ≤ 0.4) were prepared using the solid state reaction method and were confirmed to possess a cubic structure with Fm-3m space group using the X-ray diffraction analysis and Rietveld refinement. A second order of ferromagnetic phase transition was recorded in both the pure as well as the Nb doped samples using the temperature dependent magnetization and Arrott plots analysis. The pristine Ba2FeMoO6 (BFMO) sample indicated a spontaneous magnetization (34.6 emu/g at 100 K) with a relatively sharp magnetic transition at the Curie temperature (TC) of 315 K as compared to the doped samples. A magnetic entropy change of 0.93 Jkg?1K?1 at an applied magnetic field of 2.5 T was measured for the pure BFMO sample. The doped BFMO samples with Mo partially substituted by Nb however, were observed to effectively modify the TC accompanied by a decrease in magnetization. The results investigated in this work suggest that the magnetic and magnetocaloric properties of the BFMO can be tailored by controlled Nb doping which is of significant importance in order to realize the numerous potential applications of the material in the magnetic refrigeration technology. 相似文献